electron domain geometry vsepr chart table 9.3

The website provides good resources for visualizing and practicing VSEPR topics. Table 1.2 Summary of specific VSEPR shapes # of Bonding Pairs (BP) and Lone Pairs (LP) Geometry (shape) of all the electron groups To describe a certain shape, the specific name has to be used properly, and the bond angle information is important as well. The most common shapes are summarized in the following table (Table 1.2). The VSEPR shapes can be rather diverse, considering the different numbers of total electron pairs together with the different numbers of lone pairs involved. The shape of a water molecule is bent because only the atoms are counted towards the molecular shape, not the lone pair electrons. The reason is that even though the lone pairs occupy the space, there are no terminal atoms connected with lone pair, so the lone pair become “invisible” for the shape of the species.įor the example of the water (H 2O) molecule, the central oxygen atom has two BPs and two LPs, and the shape of all the electron groups is tetrahedral. However, for the species that has lone pair electrons on the central atom, the shape of the species will be different to the shape of the electron groups. Figure1.5a Tigonal bipyramidal shape of PCl5 molecule The trigonal bipyramidal shape can be drawn on paper using solid and dashed wedges: the three bonds lie within the paper plane are shown as ordinary lines, the solid wedge represent a bond that points out of the paper plane, and the dashed wedge represent a bond that points behind the paper plane. The shape of the electron groups is trigonal bipyramidal, and the shape of the PCl 5 molecule is trigonal bipyramidal as well. Multiple bonds (double or triple bond) are regarded as one electron group for VSEPR purpose.įor species that do not have any lone pair electrons (LP), the geometry (shape) of the species is just the same as the geometry of the electron groups.įor the e xample of the PCl 5 molecule, there are five electron groups on the central phosphorous, and they are all bonding pairs (BP).For VSEPR purpose, the terms “ shape” and “ geometry” are interchangeable “ electron pair” and “ electron group” are also interchangeable.Geometry (Shape) of electron groups (electron pairs) Total number of electron groups (electron pairs) around central atom Valence electron pairs are oriented to be as far apart as possible to minimize repulsions.īased on this theory, depending on the number of electron pairs (both bonding pairs and lone pairs) around the central atom, a certain shape is adopted to minimize the repulsion between election pairs, as summarized in the table below:.Electron pairs repel each other whether they are in chemical bonds or lone pairs.The Valence-Shell Electron-Pair Repulsion (VSEPR) theory helps us to understand and predict the geometry (shape) of molecules or ions.

Electron domain geometry vsepr chart table 9.3